Bài 1 :

Gọi 

\(n_{Fe} = a(mol) ; n_{Zn} = b(mol)\\ Fe + 2HCl \to FeCl_2 + H_2\\ Zn + 2HCl \to ZnCl_2 + H_2\\ \)

Ta có : 

\(\hept{\begin{cases}n_{H_2}=a+b=\frac{3,36}{22,4}=0,15\left(mol\right)\\m_{muoi}=127a+136b=19,5\left(gam\right)\end{cases}}\)

\(\Rightarrow\hept{\begin{cases}a=0,1\\b=0,05\end{cases}}\)\(\Rightarrow\hept{\begin{cases}m_{Fe}=0,1.56=5,6\left(gam\right)\\m_{Zn}=0,05.65=3,25\left(gam\right)\end{cases}}\)

Bài 2 : 

\(\hept{\begin{cases}n_{BaCO_3}=a\left(mol\right)\\n_{BaSO_3}=b\left(mol\right)\end{cases}}\)

\(BaCO_3 + 2HCl \to BaCl_2 + CO_2 + H_2O\\ BaSO_3 + 2HCl \to BaCl_2 + SO_2 + H_2O\)

Ta có : 

\(\hept{\begin{cases}m_{hh}=197a+217b=20,5\left(gam\right)\\n_{khí}=n_{CO_2}+n_{SO_2}=a+b=\frac{2,24}{22,4}=0,1\left(mol\right)\end{cases}}\)

Suy ra:  a = 0,06 ; b = 0,04

\(\%m_{BaCO_3} = \dfrac{0,06.197}{20,5}.100\% =57,66\%\\ \%m_{BaSO_3} = 100\%- 57,66\%=42,34\%\)

TN1: Gọi (n_Al; n_Zn; n_Fe) = (a; b; c)

=>27a + 65b + 56c = 20,4 (1)

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

              a----------------------->1,5a

             Zn + 2HCl --> ZnCl₂ + H₂

              b--------------------->b

              Fe + 2HCl --> FeCl₂ + H₂

               c----------------------->c

=> \(1,5a+b+c=0,45\) (2)

TN2: Gọi (n_Al; n_Zn; n_Fe) = (ak; bk; ck)

=> ak + bk + ck = 0,2 (3)

\(n_{Cl_2}=\dfrac{6,16}{22,4}=0,275\left(mol\right)\)

PTHH: 2Al + 3Cl₂ --t^o--> 2AlCl₃

            ak-->1,5ak

             Zn + Cl₂ -t^o-> ZnCl₂

            bk--->bk

              2Fe + 3Cl₂ --t^o--> 2FeCl₃

              ck--->1,5ck

=> 1,5ak + bk + 1,5ck = 0,275 (4)

(1)(2)(3)(4) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,1\left(mol\right)\\c=0,2\left(mol\right)\end{matrix}\right.\)

=> \(\%Fe=\dfrac{0,2.56}{20,4}.100\%=54,9\%\)

a) n H2 = 15,68/22,4 = 0,7(mol)

$Zn + 2HCl \to ZnCl_2 + H_2$
$Fe + 2HCl \to FeCl_2 + H_2$

Theo PTHH : nHCl = 2n H2 = 1,4(mol)

=> CM HCl = 1,4/2 = 0,7M

b) n Zn = a(mol) ; n Fe = b(mol) => 65a + 56b = 43,7(1)

n H2 = a + b = 0,7(2)

Từ (1)(2) suy ra a = 0,5 ; b = 0,2

Suy ra:

m Zn = 0,5.65 = 32,5 gam

m Fe = 0,2.56 = 11,2 gam

a) n H2 = 15,68/22,4 = 0,7(mol)

Theo PTHH : nHCl = 2n H2 = 1,4(mol)

=> CM HCl = 1,4/2 = 0,7M

b) n Zn = a(mol) ; n Fe = b(mol) => 65a + 56b = 43,7(1)

n H2 = a + b = 0,7(2)

Từ (1)(2) suy ra a = 0,5 ; b = 0,2

Suy ra:

m Zn = 0,5.65 = 32,5 gam

m Fe = 0,2.56 = 11,2 gam

Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\) => 65a + 56b + 27c = 10,65 (1)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            Fe + 2HCl --> FeCl₂ + H₂

            2Al + 6HCl --> 2AlCl₃ + 3H₂

=> \(n_{H_2}=a+b+1,5c=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) (2)

PTHH: Zn + Cl₂ --t^o--> ZnCl₂

            2Fe + 3Cl₂ --t^o--> 2FeCl₃

            2Al + 3Cl₂ --t^o--> 2AlCl₃

=> \(n_{Cl_2}=a+1,5b+1,5c=\dfrac{5,6}{22,4}=0,25\left(mol\right)\) (3)

(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,05\left(mol\right)\\c=0,05\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_{Zn}=0,1.65=6,5\left(g\right)\\m_{Fe}=0,05.56=2,8\left(g\right)\\m_{Al}=0,05.27=1,35\left(g\right)\end{matrix}\right.\)

a) \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{6,5}{10,65}.100\%=61,033\%\\\%m_{Fe}=\dfrac{2,8}{10,65}.100\%=26,291\%\\\%m_{Al}=\dfrac{1,35}{10,65}.100\%=12,676\%\end{matrix}\right.\)

b) n_HCl = 2a + 2b + 3c = 0,45 (mol)

=> m_HCl = 0,45.36,5 = 16,425 (g)

=> \(a\%=C\%=\dfrac{16,425}{200}.100\%=8,2125\%\)

c) m_{dd sau pư} = 10,65 + 200 - 0,225.2 = 210,2 (g)

=> \(\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{210,2}.100\%=6,47\%\\C\%_{FeCl_2}=\dfrac{0,05.127}{210,2}.100\%=3,02\%\\C\%_{AlCl_3}=\dfrac{0,05.133,5}{210,2}.100\%=3,176\%\end{matrix}\right.\)

giúp em vs ạ

\(n_{H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(\Rightarrow n_{HCl}=2\cdot n_{H_2}=2\cdot0.3=0.6\left(mol\right)\)

BTKL : 

\(m_{Muối}=m_{hh}+m_{HCl}-m_{H_2}=18.6+0.6\cdot36.5-0.3\cdot2=39.9\left(g\right)\)

Đáp án A

Đáp án : A

n_H2 = 0,25 mol; n_SO2 = 0,3 mol

2H⁺   + 2e → H₂                                  S⁺⁶ + 2e   → S⁺⁴

           0,5 <-- 0,25                                      0,6 <-- 0,3

n_Fe = 0,6 – 0,5 = 0,1 mol

=> m_Fe = 5,6g

Đáp án B.

Số mol của Hiđro bằng:

n H 2 = 6 , 72 22 , 4 = 0 , 3 ( m o l )

lại có  n C l - t r o n g   m u ố i = 2 n H 2 = 2 . 0 , 3 = 0 , 6

Khối lượng muối tạo thành bằng: 12,45 + 0,6. 35,5 = 33,75 (gam).